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21.
With the successful implementation of in situ chemical oxidation (ISCO) programs to remediate contaminated soil and groundwater aquifers worldwide, ISCO has become established as a traditional remediation technique. On the basis of historical success, expanded ISCO practices are now routinely applied to increasingly difficult geologic environments, including formerly problem locations such as those containing nonaqueous‐phase liquid, fractured bedrock, low‐conductivity media, and highly layered and/or heterogeneous aquifers. Effective delivery of amendment, however, remains the single most important aspect of successful remediation, particularly given the range of potentially applicable delivery methods and site complexities. Selecting the most appropriate technique for any specific site depends upon a clear understanding of the variety of site constraints, including factors such as site conditions, underlying geology, contaminant distribution, technology limitations, and other project‐specific factors. Because the injection program is often the largest cost associated with implementation of an ISCO project, it is critical to develop a cost‐effective injection method for each site. Constant head injection provides a cost‐effective alternative for sites with low‐conductivity lithology(ies). Constant head injection employs a continuous low‐pressure application method to deliver ISCO agents over a long period of time. This synergistic method complements the existing site conditions and heterogeneity, working with the natural conditions, rather than trying to overcome or destroy the site geology using highly aggressive delivery techniques. © 2014 Wiley Periodicals, Inc. 相似文献
22.
Institutional Constraints on Cost‐Effective Water Management: Selenium Contamination in Colorado's Lower Arkansas River Valley 下载免费PDF全文
Misti D. Sharp Dana L.K. Hoag Ryan T. Bailey Erica C. Romero Timothy K. Gates 《Journal of the American Water Resources Association》2016,52(6):1420-1432
Ground and surface water selenium (Se) contamination is problematic throughout the world, leading to harmful impacts on aquatic life, wildlife, livestock, and humans. A groundwater reactive transport model was applied to a regional‐scale irrigated groundwater system in the Lower Arkansas River Basin in southeastern Colorado to identify management practices that remediate Se contamination. The system has levels of surface water and groundwater Se concentrations exceeding the respective chronic standard and guidelines. We evaluate potential solutions by combining the transport model with an assessment of the cost to employ those practices. We use a framework common in economics and engineering fields alike, the Pareto frontier, to show the impact of four different best management practices on the tradeoffs between Se and cost objectives. We then extend that analysis to include institutional constraints that affect the economic feasibility associated with each practice. Results indicate that although water‐reducing strategies have the greatest impact on Se, they are the hardest for farmers to implement given constraints common to western water rights institutions. Therefore, our analysis shows that estimating economic and environmental tradeoffs, as is typically done with a Pareto frontier, will not provide an accurate picture of choices available to farmers where institutional constraints should also be considered. 相似文献
23.
Pradeep Jain Jae Hac Ko Dinesh Kumar Jon Powell Hwidong Kim Lizmarie Maldonado Timothy Townsend Debra R. Reinhart 《Waste management (New York, N.Y.)》2014,34(11):2312-2320
A case study of landfill liquids addition using small diameter (5 cm) vertical wells is reported. More than 25,000 m3 of leachate was added via 134 vertical wells installed 3 m, 12 m, and 18 m deep over five years in a landfill in Florida, US. Liquids addition performance (flow rate per unit screen length per unit liquid head) ranged from 5.6 × 10?8 to 3.6 × 10?6 m3 s?1 per m screen length per m liquid head. The estimated radial hydraulic conductivity ranged from 3.5 × 10?6 to 4.2 × 10?4 m s?1. The extent of lateral moisture movement ranged from 8 to 10 m based on the responses of moisture sensors installed around vertical well clusters, and surface seeps were found to limit the achievable liquids addition rates, despite the use of concrete collars under a pressurized liquids addition scenario. The average moisture content before (51 samples) and after (272 samples) the recirculation experiments were 23% (wet weight basis) and 45% (wet weight basis), respectively, and biochemical methane potential measurements of excavated waste indicated significant (p < 0.025) decomposition. 相似文献
24.
Perceptions matter: household adaptive capacity and capability in two Australian coastal communities
Elrick-Barr Carmen E. Thomsen Dana C. Preston Benjamin L. Smith Timothy F. 《Regional Environmental Change》2017,17(4):1141-1151
Regional Environmental Change - This paper presents empirical data on household perceptions of capability to adapt to climate hazards and associated capacity needs. Households play an important... 相似文献
25.
Yung-Ping Tseng Gerard T. Kyle C. Scott Shafer Alan R. Graefe Timothy A. Bradle Michael A. Schuett 《Environmental management》2009,43(3):496-507
Along with the growing boating population and the number of boats in use on limited inland waterways, boater expectations
of setting density, safety perceptions, and the associated impacts on their experience (e.g., satisfaction) are becoming increasingly
important. The primary purpose of this article was to explore a recreational boating crowding–satisfaction model derived from
previous work using safety and enjoyment as mediating variables. We also tested our crowding–satisfaction model among day
and overnight users. Our analysis revealed no significant difference between day and overnight users for any of the relationships
tested in our model. Our final model indicated as respondents’ expectations for seeing people increased along with their feelings
of being crowded, they were more inclined to consider the conditions on the lake as being unsafe. They were also more inclined
to indicate that the number of people they had seen on the lake detracted from their boating experience. Respondents’ satisfaction
was tied to their perceptions of crowding. Mediating variables illustrated that the relationship was conditioned by perceptions
of safety and enjoyment. Analysis of the indirect effect observed in our study illustrate that when the number of people seen
on the lake exceed respondents’ expectations, their perceptions of safety and enjoyment both decline, resulting in lower satisfaction.
These findings have implications for managing recreational boating use on inland lake systems. Given the role played by expectations
in our model, efforts to communicate with boaters about conditions on these waterways is important for helping them plan their
boating experience and avoid situations they consider unsafe or unsatisfactory. 相似文献
26.
Lynn M. Russell Ranjit Bahadur Lelia N. Hawkins James Allan Darrel Baumgardner Patricia K. Quinn Timothy S. Bates 《Atmospheric environment (Oxford, England : 1994)》2009,43(38):6100-6105
Organic aerosol chemical markers from normalized concentrations of independent measurements of mass fragments (using Aerosol Mass Spectrometry, AMS) are compared to bond-based functional groups (from Fourier Transform Infrared spectroscopy, FTIR) during eight field projects in the western hemisphere. Several field projects show weak correlations between alcohol group fractions and m/z 60 fractions, consistent with the organic hydroxyl groups and the fragmentation of saccharides, but the weakness of the correlations indicate chemical differences among the relationships for ambient aerosols in different regions. Carboxylic acid group fractions and m/z 44 fractions are correlated weakly for three projects, with correlations expected for aerosols dominated by di-acid compounds since their fragmentation is typically dominated by m/z 44. Despite differences for three projects with ratios of m/z 44 to m/z 57 fragments less than 10, five projects showed a linear trend between the project-average m/z 44 to m/z 57 ratio and the ratio of acid and alkane functional groups. While this correlation explains only a fraction of the fragment and bond variability measured, the consistency of this relationship at multiple sites indicates a general agreement with the interpretation of the relative amount of m/z 44 as a carboxylic acid group marker and m/z 57 as an alkane group marker. 相似文献
27.
Kelly P. Grogan Robert A. Fjeld Timothy A. DeVol 《Journal of environmental radioactivity》2010,101(10):847-853
The effect of the spatial variability of Kd on calculations of contaminant travel time in the vadose zone was determined. Depth discrete measurements of Kd were made for a suite of radionuclides (109Cd, 57Co, 60Co, 85Sr, 137Cs, and 88Y) utilizing a sediment core from the E-Area at the Savannah River Site. The Kd’s were ordered as 85Sr2+ < 137Cs+ < 109Cd2+ < 57Co2+ = 60Co2+ << 88Y3+ and the values generally fell below or near the lowest quartile of values reported in the literature. Correlations were generally weak between soil properties and Kd values. Most importantly, all of the Kd distributions could be reasonably approximated as log-normal. Deterministic and stochastic calculations of contaminant travel time to the water table were made. The deterministic calculations were based on each of three conceptual models of the vadose zone: complete stratification (17 strata, each with a different Kd), two strata (two sections of the vadose zone, each characterized by a single, average Kd), and unstratified (a single zone with an average Kd). Stochastic calculations were based on log-normal fits to the Kd data. The two strata model generally yielded travel times 2× greater than those in the completely stratified model. The unstratified model yielded travel times that were between 3 and 5 times greater than the completely stratified model. The stochastic mean travel times were comparable to those of the two strata model. 相似文献
28.
29.
Ryan Allen Michael Box Lee-Jane Sally Liu Timothy V. Larson 《Journal of the Air & Waste Management Association (1995)》2013,63(12):1650-1653
ABSTRACT Particulate matter (PM) is a ubiquitous air pollutant that has been receiving increasing attention in recent years due in part to the association between PM and a number of adverse health outcomes, including mortality and increases in emergency room visits and respiratory symptoms, as well as exacerbation of asthma and decrements in lung function.1-5 As a result, the ability to accurately sample ambient PM has become important, both to researchers and to regulatory agencies. The federal reference method for the determination of fine PM as PM2.5 in the atmosphere recommends that particle-sampling filters be conditioned and weighed in an environment with constant temperature and relative humidity (RH).6 It is also recommended that vibration, electrostatic charges, and contamination of the filters from laboratory air be minimized to reduce variability in filter weight measurements. These controls have typically been maintained in small, environmentally controlled “cleanrooms.” As an alternative to constructing an elaborate cleanroom, we have designed, and presented in this paper, an inexpensive weighing chamber to maintain the necessary level of humidity control. 相似文献
30.
Agouridis CT Angel PN Taylor TJ Barton CD Warner RC Yu X Wood C 《Journal of environmental quality》2012,41(2):454-468
Surface mining is a common method for extracting coal in the coal fields of eastern Kentucky. Using the Forestry Reclamation Approach (FRA), which emphasizes the use of minimally compacted or loose-dumped spoil as a growth medium for trees, reclamation practitioners are successfully reestablishing forests. Yet, questions remain regarding the effects FRA has on the quality of waters discharged to receiving streams. To examine the effect of FRA on water quality, this study compared waters that were discharged from three types of spoils: predominantly brown, weathered sandstone (BROWN); predominantly gray, unweathered sandstone (GRAY); and an equal mixture of both aforementioned sandstones and shale (MIXED). The water quality parameters pH, EC, Ca, K, Mg, Na, NO-N, NH-N, SO, Cl, TC, suspended sediment concentration (SSC), settleable solids (SS), and turbidity were monitored over a 2-yr period on six 0.4-ha plots (two replications per spoil type). Generally, levels of Cl, SO, Ca, NO-N, NH-N, SS, SSC, and turbidity decreased over time. The pH for all spoils increased from about 7.5 to 8.5. The EC remained relatively level in the BROWN spoil, whereas the GRAY and MIXED spoils had downward trajectories that were approaching 500 μS cm. The value of 500 μS cm has been reported as the apparent threshold at which certain taxa such as Ephemeroptera (e.g., Mayfly) recolonize disturbed headwater streams of eastern Kentucky and adjacent coal-producing Appalachian states. 相似文献